Search results for "Semiclassical physics"
showing 10 items of 92 documents
Line parameters and shapes of high clusters: R-branch of the nu3 band of CH4 in He mixtures
2002
International audience; The IR absorption spectra of CH4 in pure gas and in mixture with helium were studied in the region of nu3 band at higher J line clusters R(17)-R(22). The frequencies and intensities of rotation-vibration lines were estimated from the experimental spectra at Doppler shape conditions. The line frequencies and intensities were calculated and used for the attribution of overlapped lines in clusters. The calculated line intensities are close to the experimental values. The calculated frequency structure of the higher J manifolds are somewhat wider than the observed one. The shapes of helium-broadened line clusters were compared with those calculated accounting for line mi…
A Study of the Direct Spectral Transform for the Defocusing Davey‐Stewartson II Equation the Semiclassical Limit
2019
International audience; The defocusing Davey-Stewartson II equation has been shown in numerical experiments to exhibit behavior in the semiclassical limit that qualitatively resembles that of its one-dimensional reduction, the defocusing nonlinear Schrodinger equation, namely the generation from smooth initial data of regular rapid oscillations occupying domains of space-time that become well-defined in the limit. As a first step to studying this problem analytically using the inverse scattering transform, we consider the direct spectral transform for the defocusing Davey-Stewartson II equation for smooth initial data in the semiclassical limit. The direct spectral transform involves a sing…
Semiclassical approximation in the magnetic problem of exchange-coupled mixed valence clusters
1994
Abstract The frameworks of the applicability of the semiclassical adiabatic approach suggested by Borras-Almenar, Coronado and Tsukerblat to the magnetic problem of mixed valence clusters are considered in a model taking into account magnetic exchange, double exchange and vibronic interaction. The results for the quantum-mechanical and semicalssical calculation of the temperature-variable magnetic moments are compared with those within the scope of the semiclassical approximation for the dimeric d 1 —d 2 clusters and trimeric d 1 —d 1 —d 2 systems with partial delocalization over a pair of ions. The semiclassical approach describes with high accuracy the temperature dependencies of the magn…
Semiclassical Methods for the Description of Large Metal Clusters
1996
One of the most fascinating aspects of clusters is that they can be made arbitrarily large and therefore provide links between the microscopic and the macroscopic world. It is challenging to study how their physical properties change when going from atoms and small molecules to the bulk limit of condensed matter. But also the models and mathematical tools themselves, which are used in order to tackle the many-body problem, are an object of study for the theoretician. In particular, the question of how far quantum-mechanics must be carried with increasing size and where classical pictures become appropriate is of great interest. In this spirit, we discuss here some semiclassical methods for …
Critical energy flux and mass in solvable theories of 2D dilaton gravity
1998
In this paper we address the issue of determining the semiclassical threshold for black hole formation in the context of a one-parameter family of theories which continuously interpolates between the RST and BPP models. We find that the results depend significantly on the initial static configuration of the spacetime geometry before the influx of matter is turned on. In some cases there is a critical energy density, given by the Hawking rate of evaporation, as well as a critical mass $m_{cr}$ (eventually vanishing). In others there is neither $m_{cr}$ nor a critical flux.
Integrable models and degenerate horizons in two-dimensional gravity
1999
We analyse an integrable model of two-dimensional gravity which can be reduced to a pair of Liouville fields in conformal gauge. Its general solution represents a pair of ``mirror'' black holes with the same temperature. The ground state is a degenerate constant dilaton configuration similar to the Nariai solution of the Schwarzschild-de Sitter case. The existence of $\phi=const.$ solutions and their relation with the solution given by the 2D Birkhoff's theorem is then investigated in a more general context. We also point out some interesting features of the semiclassical theory of our model and the similarity with the behaviour of AdS$_2$ black holes.
Experimental and theoretical study of line mixing in methane spectra. III. The Q branch of the Raman ν1 band
2000
The shape of the ν1 Raman Q branch of CH4 perturbed by Ar and He at room temperature has been studied. Stimulated Raman spectroscopy (SRS) experiments have been made in the 2915–2918 cm−1 spectral region for total pressures from 0.4 to 70 atm and mixtures of ≈5% CH4 with He and Ar. Analysis of the spectra demonstrates that the shape of the Q branch is significantly influenced by line mixing and much narrower than what is predicted by the addition of individual line profiles. For the first time, a model is proposed for the calculation and analysis of the effects of collisions on the considered spectra. In this approach, the rotational part of the relaxation matrix is constructed, with no adj…
Extending Limits of Chlorine Kinetic Isotope Effects
2012
Chlorine kinetic isotope effects exceeding semiclassical limits were observed in enzyme-catalyzed reactions, but their source has not been yet identified. Herein we show that unusually large chlorine kinetic isotope effects are associated with reactions in which chlorine is the central atom that is being passed between two heavy atoms. The origin of these large values is the ratio of imaginary frequencies for light-to-heavy species (the so-called temperature-independent factor).
Numerical Study of the semiclassical limit of the Davey-Stewartson II equations
2014
We present the first detailed numerical study of the semiclassical limit of the Davey–Stewartson II equations both for the focusing and the defocusing variant. We concentrate on rapidly decreasing initial data with a single hump. The formal limit of these equations for vanishing semiclassical parameter , the semiclassical equations, is numerically integrated up to the formation of a shock. The use of parallelized algorithms allows one to determine the critical time tc and the critical solution for these 2 + 1-dimensional shocks. It is shown that the solutions generically break in isolated points similarly to the case of the 1 + 1-dimensional cubic nonlinear Schrodinger equation, i.e., cubic…
Quadrupole deformation of Xe-130 measured in a Coulomb-excitation experiment
2020
Physical review / C 102(5), 054304 (2020). doi:10.1103/PhysRevC.102.054304